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As a result of this growing significance, new technologies were developed to carry out hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodeoxygenation (HDO), and hydrodemetallation (HDM) These allow to convert various distillate residues into valuable distillates using high-reaction-temperature, highpressure, and low-contact-time hydroprocessing units A new technology, the ISAL process, developed jointly by INTEVEP and UOP, applies a selective hydroprocessing method to produce reformulated gasoline with improved naphtha quality by reducing S, N, and olefins without octane loss 67 Hydrodesulfurization (HDS) is a well-established upgrading process designed to remove and accumulate metals and to desulfurize the feed By increasing the reaction temperature and applying suitable catalysts, the conversion of a substantial fraction of the residue into distillate can also be obtained The residue upgrading, therefore, is switching from HDS to hydrocracking The major developments in residue hydrocracking processes and catalysts were reviewed.

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268-270 Because of the changing market conditions and requirements, specifically, a steady, further growth of the market and environmental pressure on product quality, hydroprocessing and hydrotreatment operations have growing significance As a result, new methods and catalysts based on a thorough knowledge of existing commercial operations were developed 7! Hydroprocessing was originally developed mainly because low-cost hydrogen was available from catalytic reforming In addition, the oil price hikes in the 1970s and environmental regulations also contributed to its growing importance In the future, refiners are expected to continue to rely on hydroprocessing to meet new product quality specifications With the necessity to convert residue and to remove sulfur, refiners usually tum to hydroprocessing.

prd-start <= O ; div-start <= O ; b2b-start <= O ; case s t a t e - r e g i s when i d l e = > i f s t a r t = l then s t a t e - n e x t <= c o u n t ; p r d - s t a r t <= 1 ;

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Two approaches have been very popular, and IFP has excellent technologies, which serve both of these 7! The fixed-bed Hyvahl process is uniquely suited for upgrading atmospheric or low-metal-content vacuum residues for the production of lowsulfur fuel oil or as a feedstock to the residue FCC unit For processing moderate-tohigh metal vacuum residues the H-Oil process based on the ebullated-bed system, is the preferred choice New developments in FCC, resid FCC, hydrotreatment, and hydroprocessing operations are treated in review papers272-275 and symposia proceedings 276,277 Books addressing various problems of FCC 278 ,279 and a detailed analysis of both technological aspects and fundamental knowledge of hydrotreating catalysis280 are also available The catalysts applied in hydroprocessing operations are typically sulfided CoO-Mo03-AI 20 3 or NiO-Mo0 3-AI 20 3.

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The results of relevant studies 28 ! and the application in refinery processes of these and other transition-metal sulfide catalysts were reviewed 82 Selection of catalysts and reactors for particular feeds and products is also an important issue 57,280,283,284 Extensive studies describe the development of new materials, such as transitionmetal nitrides 285 ,286 and oxynitrides,287,288 as new potential catalysts for hydroprocessing operations Studies were performed to acquire information on the effect of high levels of ZSM-5 additive on light olefins and gasoline composition in FCC 289 It was found that ZSM-5 can substantially increase propylene and butenes, and.

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