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To work this problem without a calculator with a square root key, rewrite the equation as 16 10 12 = x2 The left side is now two perfect squares and the solution is easily obtained as 40 10 6 M = x 28 Answer: A The spontaneity of a reaction is given by the value of the free energy, G , which is de ned by: G = H T S If the value of G is negative, the reaction is spontaneous (product favored), a positive value means the reverse reaction is spontaneous, and a value of 0 means the system is at equilibrium For this reaction, the H term is negative and the term T S is also negative, because S is positive The two terms make the overall value of G negative, which means the reaction is spontaneous as written 29 Answer: C The species that is reduced will have a decrease in the oxidation number The oxidation number of each species is given in the equation below Ca(s)+Sn2+(aq) Ca2+(aq)+Sn(s) 0 +2 +2 0 The oxidation number of Ca changes from 0 to +2, which is an oxidation The Sn changes from +2 to 0, which is a reduction The Sn2+ ion picks up two electrons and is reduced to Sn metal The correct half reaction for the species that is reduced is: Sn2+(aq) + 2 e Sn(s) 30 Answer: C Choice A is a termination step, and choice B is a highly endothermic fragmentation Choice D resembles a propagation step, but it actually consumes product Choice C obeys all the guidelines of a propagation step: it provides a continuation of the radical cycle, it consumes stoichiometric reagent, and it provides one of the observed products 31 Answer: C Since the rst step in bromination is highly endothermic, the transition state energies resemble those of the intermediate carbon radicals This is why bromination is a selective process Therefore, the most highly substituted center is most rapidly brominated 32 Answer: D This step represents bond formation, which is always exothermic; therefore, H is negative Since two species are combining to form one, translational degrees of freedom are lost, and S is also negative 33 Answer: D The Baeyer-Villiger reaction converts ketones to esters; thus choices C and D are the most valid These two choices differ with regard to which alkyl group has migrated.

If you ve worked with the Device Manager in previous editions of Windows (such as Windows XP), you ll be happy to know that much of the functionality is the same

The Device Manager requires administrative permissions to make any changes If you are logged in as an administrator, then the User Account Control dialog will appear prompting you to continue If you are logged in with a standard user account, you will access Device Manager in Read-only mode You can access the Device Manager in a few different ways

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Click Start and then click Control Panel Click System and Maintenance Click System In the Tasks pane on the left, click Device Manager Click Start, right-click Computer, and select Properties This is the same System window that you can access from the Control Panel In the Tasks pane on the left, click Device Manager Click Start, right-click Computer, and select Manage If the User Account Control dialog box appears, click Continue In the left pane under System Tools, click Device Manager Click Start In the Start Search box, enter mmc devmgmtmsc

Once launched, the Device Manager looks similar to Figure 3-1 One of the great things about the Device Manager is that when things are wrong, they jump out at you For example, in Figure 3-1, the Sound, Video, and Game Controllers node is opened and the Realtek High Definition Audio device has a down arrow icon This indicates the device is disabled Any device can be enabled or disabled within the Device Manager, by simply rightclicking the device and selecting Enable (when it is disabled) or Disable (when it is enabled) Additionally, you may see a device with a black question mark or a black exclamation mark in a yellow circle These icons often indicate a problem with the driver EXAM TIP If a device has a down arrow on the icon, it is disabled Before you can use the device, you must enable it If the device has a yellow circle with a black question mark or black exclamation mark, there is likely a problem with the driver

Drivers are the files that an operating system uses to communicate with devices Without the proper driver, even the best hardware is nothing more than a useless mass of silicon Thankfully, Plug and Play technology automatically installs and configures drivers for many pieces of hardware you may install When Plug and Play doesn t work is when you need to get involved

When a device is detected, the Plug and Play service is notified The Plug and Play service queries the device to retrieve an identifier Using this identifier, Plug and Play attempts to locate a driver The following locations are searched:

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